NAI's University of Wisconsin team presents a review of iron isotope fingerprints created through biogeochemical cycling in the May, 2008 issue of Annual Review of Earth and Planetary Sciences. This landmark paper brings together for the first time the co-evolution records of photosynthesis, bacterial sulfate reduction, and bacterial iron reduction in the early Earth. They review data on natural systems and experiments, looking at both abiological and biological processes, and conclude that the temporal carbon, sulfur, and iron isotope record reflects the interplay of changing microbial metabolisms over Earth's history.